Mahadeva gave Brahmastra to Sage Agastya. Agastya gave it to Agnivesa. Agnivesa gave it to Drona. Drona gave it to Arjuna.
The definition of Itihasa is इतिह आस्ते अस्मिन् - it contains advice for leading a meaningful life. They are based on real incidents of the past. The definition of Purana is पुरातनवृत्तान्तकथनम् - Puranas are narrations of past incidents. Itihasas are centered around a particular theme; Ramayana around Rama's life and Mahabharata around the Kuru Vamsha. A book can be called Purana only if it contains the following five: 1. Sarga - description of primary creation. 2. Pratisarga - description of secondary creation. 3. Vamsha - description of important Vamshas such as Surya Vamsha and Chandra Vamsha. 4. Manvantara - description of the 14 Manvantaras, Manus, Devas, Rishis, and avataras. 5. Vamshanucharita - description of the important persons in the Vamshas. पुराणं पञ्चलक्षणम् - Puranas should have these five characteristics.
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Ganapathy
Shiva
Hanuman
Devi
Vishnu Sahasranama
Mahabharatam
Practical Wisdom
Yoga Vasishta
Vedas
Rituals
Rare Topics
Devi Mahatmyam
Glory of Venkatesha
Shani Mahatmya
Story of Sri Yantra
Rudram Explained
Atharva Sheersha
Sri Suktam
Kathopanishad
Ramayana
Mystique
Mantra Shastra
Bharat Matha
Bhagavatam
Astrology
Temples
Spiritual books
Purana Stories
Festivals
Sages and Saints